| 2-磺酸基二苯胺-4-重氮盐制备及其光、热分解性质 |
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| 引用本文： | 赵超,卢英先,曹维孝.2-磺酸基二苯胺-4-重氮盐制备及其光、热分解性质[J].影像科学与光化学,1998,16(1):55-59. |
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| 作者姓名： | 赵超 卢英先 曹维孝 |
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| 作者单位： | 北京大学化学与分子工程学院, 北京 100871 |
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| 基金项目： | 国家自然科学基金资助项目(批准号:59633110) |
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| 摘 要： | 二苯胺重氮盐由于每个分子中有二个苯环,其中末键连重氮基的苯环可与甲醛在酸性介质中发生缩聚反应1~3],形成的重氮树脂具有良好的感光性能,并可溶于有机溶剂或碱性显影液,极适合于制备感光胶印版,已发展成为阴图PS版最重要的感光剂4~7].
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| 关 键 词： | 取代二苯胺-4-重氮盐 分子内盐结构 光热分解 |
| 收稿时间： | 1997-03-10 |
SYNTHESIS OF 2 SULFONIC DIPHENYLAMINE 4 DIAZONIUM SALT AND ITS PHOTO AND THERMODECOMPOSITION |
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| ZHAO Chao,LU Yingxian,CAO Weixiao.SYNTHESIS OF 2 SULFONIC DIPHENYLAMINE 4 DIAZONIUM SALT AND ITS PHOTO AND THERMODECOMPOSITION[J].Imaging Science and Photochemistry,1998,16(1):55-59. |
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| Authors: | ZHAO Chao LU Yingxian CAO Weixiao |
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| Affiliation: | College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China |
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| Abstract: | 2-Sulfonic diphenylamine-4-diazonium salt(SDPDS) was prepared from 4-chloronitrobenzene as starting material via four steps with overall yield of about 50%. SDPDS,different from the common diazonium salt,is insoluble in water because of its intra molecular salty structure. The photo-and thermodecomposition of SDPDS were also investigated. The results show that SDPDS exhibit excellent thermostability as well as high photosensitive behaviors. |
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| Keywords: | substituted diphenylamine-4-diazonium salt intramolecular salty structure photo-and thermodecomposition |
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