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合成四苯基卟啉及其衍生物的新方法
引用本文:郭灿城,何兴涛,邹纲要.合成四苯基卟啉及其衍生物的新方法[J].有机化学,1991,11(4):416-419.
作者姓名:郭灿城  何兴涛  邹纲要
作者单位:湖南师范大学化学系,湖南师范大学化学系,湖南师范大学化学系 湖南,长沙410006,湖南,长沙410006,湖南,长沙410006 湖南师范大学八九届本科毕业生
基金项目:国家自然科学基金资助课题
摘    要:目前文献中合成四苯基卟啉(TPPH_2)和取代四苯基卟啉都是采用 Adler 方法。在酸性介质中,一些对酸敏感的卟啉化合物的合成受

关 键 词:四苯基卟啉  合成  催化  紫外-可见光谱

A New Synthetic Method for TPPH_2 and It's Derivatives
GUO Can-Cheng HE Xing-Tao ZHOU Gang-Yiao.A New Synthetic Method for TPPH_2 and It''s Derivatives[J].Chinese Journal of Organic Chemistry,1991,11(4):416-419.
Authors:GUO Can-Cheng HE Xing-Tao ZHOU Gang-Yiao
Affiliation:GUO Can-Cheng~* HE Xing-Tao ZHOU Gang-Yiao
Abstract:A new method for the synthesis of tetraphenylporphyrin(TPPH_2)and it's derivatives is reported.In the presence of AlCl_3,direct condensation of pyrrole with benzaldehyde in refuxing DMF gave TPPH_2.The yield and purity of TPPH_2 were higher than those from known literature methods.The yield was found to be related to the catalyst,so-lvent,the reaction time as well as the concentration of the reactants.Based on these resultsa probable mechanism for this reaction was suggested.
Keywords:TPPH_2  Synthesis  Catalyze  UV-Vis spectra  
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