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Optical Constants of Palladium Phthalocyanine Derivative Thin Films
作者姓名:吴谊群  陈耐生
作者单位:[1]ShanghaiInstituteofPticsandFineMechanics,ChineseAcademyofSciences,POBox800-211,Shanghai201800;LaboratoryofFunctionalMaterials,HeilongjiangUniversity,Haerbin150080 [2]DepartmentofCh,ChineseAcademyofSciences,POBox800-211,Shanghai201800;LaboratoryofFunctionalMaterials,HeilongjiangUniversity,Haerbin150080
摘    要:Ellipsometric parameters of a series of spin-coated thin films of palladium phthalocyanine derivatives with broine and tetraalkoxyl substitutes(PdPc(OC8H17)4Brm,m=0,2,3,4)are determined from a rotating analyserpolarizer type of scanning ellipsometer.The optical,dielectric constants and absorption coefficients of the films in the 500-800nm wavelength region are reported.The results show that refractive index N(N=n-k),dielectric constant ε(ε=ε1-ε2)and absorption coefficient α in the region 500-800nm are influenced by bromine atom substituted on the conjugated phthalocyanine ring regularly.It is found that there is approximately a linear relationship between the resonance absorption wavelengths of the films and the number of bromine atoms substituted on the phthalocyanine ring.

关 键 词:薄膜  钯酞菁衍结构  光学常数
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