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Enhanced Nonlinear Absorption and Optical Limiting Properties of Organic Material ZnTBP—CA—PhR in a DA—ET System
引用本文:于世瑞,赵有源,李潞瑛.Enhanced Nonlinear Absorption and Optical Limiting Properties of Organic Material ZnTBP—CA—PhR in a DA—ET System[J].中国物理快报,2003,20(7):1070-1073.
作者姓名:于世瑞  赵有源  李潞瑛
作者单位:DepartmentofOpticalScienceandEngineering,StateKeylaboratoryofAdvancedPhotonicMaterialsandDevices,FudanUniversity,Shanghai200433
摘    要:Nonlinear absorption of the organic material Zn-tetrabenzoporphin-cronicacid-phenonxy resin(ZnTBP-CA-PhR) in the donor-acceptor energy-transfer(DA-ET) system is investigated by the irradiation of Ar^ laser on its solid film.A reverse saturable absorption and an enhanced second reverse saturable absorption called the rereverse saturable absorption are observed in a visible wavelength range.The high performance of optical limiting of the sample possessing low input threshold and an over 95% linear transmission ratio are observed.The physical mechanism of rereverse satruable absorption is analysed by a five-level rate-equation simulating.According to the Huygens wave diffraction principle and the combination of Kerr effect,thermo-optic effect and optical absorption variation,a mathematical model for the optical limiting of ZnTBP-CA-PhR film limiter is established and the theoretical simulating gives a good agreement with the experimental results.

关 键 词:有机材料  DA-ET系统  能量变换  非线性光学性质  非线性吸收  光限制性质  ZnTBP-CA-PhR  
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