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Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^+-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation
引用本文:朱斌,戴晔,马洪良,林耿,邱建荣.Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^+-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation[J].中国物理快报,2008,25(1):133-136.
作者姓名:朱斌  戴晔  马洪良  林耿  邱建荣
作者单位:[1]State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 [2]Instrumental Analysis and Research Center, Shanghai University, Shanghai 200444 [3]Department of Physics, Shanghai University, Shanghai 200444
基金项目:Supported by the National Natural Science Foundation of China under Grant No 50672087, and the National Basic Research Programme of China under Grant No 2006CB806000b.
摘    要:The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearity is precipitated in Sm^3+-doped BaO-TiO2-SiO2 glass by a focused 800hm, 250 kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f-f transitions of Sm^3+ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2 TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed.

关 键 词:铁电晶体  Ba2TiSi2O8  氧化钡  二氧化钛  二氧化硅  玻璃  钐掺杂  毫秒激光辐射
收稿时间:2007-07-03

Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3+-Doped BaO--TiO2--SiO2 Glass by Femtosecond Laser Irradiation
ZHU Bin,DAI Ye,MA Hong-Liang,LIN Geng,QIU Jian-Rong.Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3+-Doped BaO--TiO2--SiO2 Glass by Femtosecond Laser Irradiation[J].Chinese Physics Letters,2008,25(1):133-136.
Authors:ZHU Bin  DAI Ye  MA Hong-Liang  LIN Geng  QIU Jian-Rong
Affiliation:State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027Instrumental Analysis and Research Center, Shanghai University, Shanghai 200444Department of Physics, Shanghai University, Shanghai 200444
Abstract:The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearityis precipitated in Sm3+-doped BaO--TiO2--SiO2 glass by a focused 800nm, 250kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f--f transitions ofSm3+ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed.
Keywords:42  70  Ce  78  55  -m  81  10  Jt
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