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Analysis of X-Ray Photoelectron Spectroscopy of Polymethyl Methacrylate Etched by a KrF Excimer Laser
作者姓名:朱效立  刘世炳  陈涛  蒋毅坚  左铁钏
作者单位:CollegeofLaserEngineering,BeijingUniversityofTechnology,Beijing100022
摘    要:The C ls and 0 ls electrons in polymethyl methacrylate etched by different incident laser intensities are analysed by x-ray photoelectron spectroscopy. The results show that when the incident laser fluence increases gradually,the percentage of carbon atoms in C-C bonds decreases while the one in carbonyl group (C=O) and alkoxy group (C-O) increases, and the percentage of oxygen atoms in C=O bonds increases while the one in C-O bonds decreases. Based on the analysis of the chemical structure, the energy level transition, energy diversion, and dissociation of bonds are theoretically examined, which is consistent with the experimental results.

关 键 词:X-射线光电子分光镜  有机玻璃  KrF受激准分子激光  刻蚀工艺
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