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Luminescent Properties and Mechanism of Gd1-x-yAlO3Eux,REy
作者姓名:罗岚  刘庆峰  刘茜
作者单位:[1]SchoolofMaterialScienceandEngineering,NanchangUniversity,Nanchang330047//"StateKeyLaboratoryofHighPerformanceCeramicsandSuperfineMicrostructure,ShanghaiInstituteofCeramics,ChineseAcademyofSciences,Shanghai200050 [2]StateKeyLaboratoryofHighPerformanceCeramicsandSuperfineMicrostructure,~hanghaiInstituteotC'eramics,ChineseAcademyofSciences,Shanghai200050
摘    要:GAP:Eu,Re(Gd1-x-yAlO3Eux,REy?A,RE=Pr or Ce) powders were prepared by a nitrate-citrate process. It is found that luminescent intensity decreases when GAP:Eu is co-doped with Pr or Ce. The phenomena of spectra prove that there is a resonant energy transfer between Eu and Pr, by the absorption and emission of lower-energy phonon, and also Ce sensitizer decreases the activator energy level from host→Eu. The two factors are considered to be the main reasons for decrease of the luminescent intensity for the co-doped GAP:Eu,Re.

关 键 词:发光性质  力学性质  硝酸盐-柠檬酸盐处理  能量转化
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