| Zero-field splitting parameters and local structures for tetragonal Cr2＋ centers in Cr2＋-doped ZnSe semiconductors |
| |
| 引用本文： | 卢婷婷,邝小渝,李辉,李洪洪,武志燕,毛爱杰.Zero-field splitting parameters and local structures for tetragonal Cr2＋ centers in Cr2＋-doped ZnSe semiconductors[J].中国物理 B,2014(11):470-473. |
| |
| 作者姓名： | 卢婷婷 邝小渝 李辉 李洪洪 武志燕 毛爱杰 |
| |
| 作者单位： | Institute of Atomic and Molecular Physics, Sichuan University |
| |
| 基金项目： | Project supported by the National Natural Science Foundation of China （Grant Nos. 11274235 and 11104190） and the Doctoral Education Fund of Education Ministry of China （Grant No. 20110181120112）. |
| |
| 摘 要： | The inter-relation between zero-field splitting （ZFS） parameters and local lattice structures of the （CrSe4）6 clusters in ZnSe semiconductors has been established by using the complete diagonalization （of the energy matrix） method. On the basis of this, the local lattice distortions, the ZFS parameters D, a, F and the optical spectrum for Cr2＋ ions doped into ZnSe are theoretically investigated, and the contributions of the spin singlets have been taken into account. The calculated ZFS parameters are in good agreement with the experimental values. From our calculations, the tetragonal distortion parameters AR = 0.091A and Aθ = 4.28° of Cr2＋ in ZnSe are acquired, and the results suggest that there exists a tetragonal expansion distortion for the local lattice structure of （CrSe4）6- clusters in ZnSe crystals. The influence of the spin singlets on ZFS parameters is also discussed, indicating that the contributions to ZFS parameters a and F cannot be ignored.
|
| 关 键 词： | 零场分裂 Cr2 半导体 局部结构 掺杂 ZnSe晶体 硒化锌 完全对角化方法 |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
