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ZnO nanorod arrays with tunable size and field emission properties on an ITO substrate achieved by an electrodeposition method
Authors:Gong Jiang-Feng  Dou Zhao-Ming  Wang Zhi-Qiang  Zhang Bo  Zhu Wei-Hua  Zhang Kai-Xiao  Liu Ming-Yi  Zhu Hao  Zhou Jian-Feng
Affiliation:a. Department of Physics, Hohai University, Nanjing 210098, China;b. National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China;c. College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
Abstract:In the present work, vertically aligned ZnO nanorod arrays with tunable size are successfully synthesized on nonseeded ITO glass substrates by a simple electrodeposition method. The effect of growth conditions on the phase, morphology, and orientation of the products are studied in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). It is observed that the as-prepared nanostructures exhibit a preferred orientation along c axis, and the size and density of the ZnO nanorod can be controlled by changing the concentration of ZnCl2. Field emission properties of the as-synthesized samples with different diameters are also studied, and the results show that the nanorod arrays with a smaller diameter and appropriate rod density exhibit better emission properties. The ZnO nanorod arrays show a potential application in field emitters.
Keywords:ZnO nanorod  microstructure  electrodeposition  field emission properties
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