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Perforated nanocap array: Facile fabrication process and efficient surface enhanced Raman scattering with fluorescence suppression
Authors:Wang Jun  Huang Li-Qing  Tong Hui-Min  Zhai Li-Peng  Yuan Lin  Zhao Li-Hua  Zhang Wei-Wei  Shan Dong-Zhi  Hao Ai-Wen  and Feng Xue-Hong
Affiliation:Non-equilibrium Condensed Matter and Quantum Engineering Laboratory, School of Science, Xi’an Jiaotong University, Xi’an 710049, China
Abstract:Recently, individual reduced-symmetry metal nanostructures and their plasmonic properties have been studied extensively. However, little attention has been paid to the approach to fabricating ordered reduced-symmetry metal nanostructure arrays. In this paper, a novel perforated silver nanocap array with high surface-enhanced Raman scattering (SERS) activity and fluorescence suppression is reported. The array is fabricated by electron beam evaporating Ag onto the perforated barrier layer side of a hard anodization (HA) anodic aluminum oxide (AAO) template. The morphology and optical property of the perforated silver nanocap array are characterized by an atomic force microscope (AFM), a scanning electron microscope (SEM), and absorption spectra. The results of SERS measurements reveal that the perforated silver nanocap array offers high SERS activity and fluorescence suppression compared with an imperforated silver nanocap array.
Keywords:reduced-symmetry structures  perforated nanocap array  surface-enhanced Raman scattering  anodic aluminum oxide
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