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Microstructure and structural phase transitions in iron-based superconductors
Authors:Wang Zhen  Cai Yao  Yang Huai-Xin  Tian Huan-Fang  Wang Zhi-Wei  Ma Chao  Chen Zhen  and Li Jian-Qi
Affiliation:Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Abstract:Crystal structures and microstructural features, such as structural phase transitions, defect structures, and chemical and structural inhomogeneities, are known to have profound effects on the physical properties of superconducting materials. Recently, many studies on the structural properties of Fe-based high-T c superconductors have been published. This review article will mainly focus on the typical microstructural features in samples that have been well characterized by physical measurements. (i) Certain common structural features are discussed, in particular, the crystal structural features for different superconducting families, the local structural distortions in the Fe2Pn2 (Pn = P, As, Sb) or Fe2Ch2 (Ch = S, Se, Te) blocks, and the structural transformations in the 122 system. (ii) In FeTe(Se) (11 family), the superconductivity, chemical and structural inhomogeneities are investigated and discussed in correlation with superconductivity. (iii) In the K0.8Fe1.6+x Se2system, we focus on the typical compounds with emphasis on the Fe-vacancy order and phase separations. The microstructural features in other superconducting materials are also briefly discussed.
Keywords:Fe-based superconductor  structural transition  structural inhomogeneity  phase separation
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