Optical properties of phosphate glasses co-doped with Yb~(3+) and silver nanoparticles |
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作者姓名: | M.A.Vallejo H. ;M.A.Martinez G. ;A.V.Kiryanov ;J.L.Lucio M. |
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作者单位: | [1]Centro de Investigaciones en Optica, Loma del Bosque 115, Col. Lomas del Campestre, Leon 37150, Guanajuato, Mexico; [2]Division de Ciencias e Ingenierias del Campus Leon de la Universidad de Guanajuato. Loma del Bosque 103, Col. Lomas del Campestre 37150, Leon Guanajuato, Mexico |
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基金项目: | financially supported by the CONACy T(Grant No.CB-2009-136186-F) |
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摘 要: | We report the fabrication and spectroscopic characterization of Yb^3+-doped phosphate glass, also containing silver nitrate. Scanning electron microscopy(SEM) provides the evidence of the formation of silver nano-particles(SNPs), which are formed as a consequence of melting and thermal decomposition of Ag NO3. Absorption spectra of the samples in the visible-to-near-infrared spectral range reveal the presence of bands centered at 410 nm associated with the SNP-plasmon resonance, and at 976 nm due to the Yb^3+. Under 916-nm laser-diode pumping, the effect of the SNP reflects that: i) the fluorescence in the 950-nm–1150-nm spectral range is strongly enhanced(~ 30 times), while the fluorescence decay time associated with the ^2F5/2→^2F7/2transition of Yb^3+ increases 25%, and ii) the basic lasing properties(saturation pumping intensity, the emission and absorption cross sections) are substantially improved.
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关 键 词: | 银纳米颗粒 磷酸盐玻璃 共掺杂 光学特性 荧光衰减时间 单核苷酸多态性 扫描电子显微镜 激光二极管泵浦 |
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