| Effect of the reagent vibration on stereodynamics of the reaction O（^1D）＋HF→F＋OH |
| |
| 引用本文： | 许燕,赵娟,岳大光,刘浩,郑晓云,孟庆田.Effect of the reagent vibration on stereodynamics of the reaction O（^1D）＋HF→F＋OH[J].中国物理 B,2009,18(12):5308-5312. |
| |
| 作者姓名： | 许燕 赵娟 岳大光 刘浩 郑晓云 孟庆田 |
| |
| 作者单位： | College of Physics and Electronics, Shandong Normal University,
Jinan 250014, China |
| |
| 基金项目： | Project supported by the National
Natural Science Foundation of China (Grant No 10574083) and the
Natural Science Foundation of Shandong Province of China (Grant No
Y2006A23), and partially by the National Basic Research Program of
China (Grant No 2006CB8 |
| |
| 摘 要： | This paper studies the influence of the reagent vibration
on the reaction O(1D)+HF → HO+F by using a quasi-classical
trajectory method on the new \textitab initio 1A' ground
singlet potential energy surface (Gómez-Carrasco et al
2007 Chem. Phys. Lett. 435 188--193). The product
angular distributions which reflect the vector correlation are
calculated. Four polarization-dependent differential cross sections
(PDDCSs) which are sensitive to many photoinitiated bimolecular
reaction experiments are presented in the center of the mass frame,
respectively. The differential cross section indicates that the OH
product mainly tends to the forward scattering, and other PDDCSs are
also influenced by the vibration levels of HF.
|
| 关 键 词： | vector correlation polarization-dependent differential cross section vibration of the reactant molecule quasi-classical trajectory |
| 收稿时间： | 1/6/2009 12:00:00 AM |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《中国物理 B》浏览原始摘要信息 |
|
点击此处可从《中国物理 B》下载免费的PDF全文 |
|
