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Zinc polyoxometalate on activated carbon: an efficient catalyst for selective oxidation of alcohols with hydrogen peroxide
Authors:Elham Assady  Bahram Yadollahi  Mostafa Riahi Farsani  Majid Moghadam
Affiliation:1. Department of Chemistry, University of Isfahan, Isfahan, Iran;2. Young Researchers and Elite Club, Islamic Azad University, Shahrekord Branch, Shahrekord, Iran
Abstract:PW11ZnO39]5? was immobilized on activated carbon and characterized using Fourier transform infrared, X‐ray diffraction, Brunauer–Emmett–Teller and elemental analysis techniques. Effective oxidation of various alcohols with hydrogen peroxide was performed in the presence of this catalyst. Easy separation of the catalyst from the reaction mixture, cheapness, high activity and selectivity, stability as well as retained activity in subsequent catalytic cycles make this supported catalyst suitable for small‐scale synthesis. Copyright © 2015 John Wiley & Sons, Ltd.
Keywords:catalysis  polyoxometalate  activated carbon  alcohol  oxidation  hydrogen peroxide
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