Pd(0)‐ S‐propyl‐2‐aminobenzothioate immobilized onto functionalized magnetic nanoporous MCM‐41 as efficient and recyclable nanocatalyst for the Suzuki,Stille and Heck cross coupling reactions |
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| Authors: | Mohsen Nikoorazm Farshid Ghorbani Arash Ghorbani‐Choghamarani Zahra Erfani |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science, Ilam University, Ilam, Iran;2. Department of Environment, Faculty of Natural Resource, University of Kurdistan, Sanandaj, Iran |
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| Abstract: | The present work describes the use of Pd(0)‐ S‐propyl‐2‐aminobenzothioate Complex immobilized onto functionalized magnetic nanoporous MCM‐41(Fe3O4@MCM‐41@Pd‐SPATB) as efficient and recyclable nano‐organometallic catalyst for C–C bond formation between various aryl halides with phenylboronic acid (Suzuki reaction), aryl halides with triphenyltin chloride (Stille reaction), and aryl halides with n‐butyl acrylate (Heck reaction). All the reactions were carried out in PEG‐400 as green solvent with short reaction time and good to excellent yields. This catalyst was characterized by FT‐IR spectroscopy, XRD, TGA, VSM, ICP‐OES, TEM, EDX and SEM techniques. Ease of operation, high efficiency, recovery and reusability for five continuous cycles without significant loss of its catalytic activities or metal leaching are the noteworthy features of the currently employed heterogeneous catalytic system. |
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| Keywords: | C‐C bond formation Fe3O4@MCM‐41@Pd‐SPATB heck reaction Stille reaction Suzuki reaction |
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