The reduction of 4‐nitrophenol and 2‐nitroaniline by palladium catalyst based on a KCC‐1/IL in aqueous solution |
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| Authors: | Sakineh Esfandiari Baghbamidi Asadollah Hassankhani Esmael Sanchooli Seyed Mohsen Sadeghzadeh |
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| Affiliation: | 1. Bandar Abbas Branch, Islamic Azad University, Bandar Abbas, Iran;2. Department of New Materials, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran;3. Department of Chemistry, University of Zabol, Zabol, Iran;4. Department of Chemistry, Faculty of Sciences, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran |
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| Abstract: | KCC‐1/IL/Pd NPs can used as an excellent support for the synthesis of highly sparse homogeneous catalyst. KCC‐1 has high surface area that was functionalized with ionic liquid phase acting as the strong performers so that the Pd catalyst was well‐dispersed without aggregation on the framework of the KCC‐1/IL. This nano catalyst was specified by TGA, XRD, TEM, SEM, FT‐IR, and ICP. For reduction of 2‐nitroaniline and 4‐nitrophenol used from the KCC‐1/IL/Pd NPs as a green catalyst that showed excellent catalytic activities. Compared with the traditional substrate, KCC‐1 substantially increases protection and the accessibility of the nanoparticle sites due to its three dimensional hierarchical structure. |
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| Keywords: | green chemistry heterogeneous catalyst ionic liquid KCC‐1 one‐pot synthesis |
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