A one‐pot method for synthesis of reduced graphene oxide‐supported Cu–Cu2O and catalytic application in tandem reaction of halides and sodium azide with terminal alkynes |
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| Authors: | Zhuofei Li Hongyan Zhao Huatao Han Jinyi Song Yang Liu Weihao Guo Zhizhong Sun Wenyi Chu |
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| Affiliation: | 1. School of Chemistry and Materials Science, Heilongjiang University, Harbin, People's Republic of China;2. Key Laboratory of Chemical Engineering Process and Technology for High‐Efficiency Conversion, College of Heilongjiang Province, Harbin, People's Republic of China |
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| Abstract: | Reduced graphene oxide (RGO)‐supported Cu–Cu2O nanocomposite material (Cu‐Cu2O@RGO) was prepared through a one‐pot reflux synthesis method. The morphology, crystal structure and composition of the prepared Cu‐Cu2O@RGO were characterized using transmission electron microscopy, X‐ray diffraction, and X‐ray photoelectron, infrared and Raman spectroscopies. Cu‐Cu2O@RGO as a heterogeneous catalyst was applied to tandem reactions of halides and sodium azide with terminal alkynes to synthesize effectively 1,4‐disubstituted 1,2,3‐triazoles. Moreover, the catalyst showed excellent recyclability performance with very little leaching of the metal. Compared with homogeneous catalysts, Cu‐Cu2O@RGO as a green and efficient catalyst was recoverable, easy to separate and highly stable in the tandem method for the synthesis of 1,2,3‐triazole compounds. |
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| Keywords: | 1 4‐disubstituted 1 2 3‐triazoles Cu‐Cu2O@RGO halides tandem reaction terminal alkynes |
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