| 竹红菌甲素和吲哚类化合物的相互作用 |
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| 引用本文： | 第五振军,张曼华,蒋丽金.竹红菌甲素和吲哚类化合物的相互作用[J].影像科学与光化学,1988,6(3):26-31. |
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| 作者姓名： | 第五振军 张曼华 蒋丽金 |
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| 作者单位： | 中国科学院感光化学研究所 北京 |
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| 摘 要： | 本文利用吸收光谱,荧光光谱研究了竹红菌甲素(以下简称HA)和吲哚类化合物的相互作用。发现HA和吲哚类化合物在一定条件下可形成复合物。这种复合物带有电荷转移性质。吲哚环上带有给电子取代基,位阻小,溶剂的极性大和溶液呈中性有利于该复合物的形成。
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| 关 键 词： | 竹红菌甲素 吲哚 复合物 相互作用 |
| 收稿时间： | 1987-04-27 |
THE INTERACTION BETWEEN HYPOCRELLIN A AND INDOLES |
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| DIWU ZHEN-JUN,ZHANG MAN-HUA,JIANG LI-JIN.THE INTERACTION BETWEEN HYPOCRELLIN A AND INDOLES[J].Imaging Science and Photochemistry,1988,6(3):26-31. |
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| Authors: | DIWU ZHEN-JUN ZHANG MAN-HUA JIANG LI-JIN |
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| Affiliation: | Institute of Photographic Chemistry, Academia Sinica, Beijing |
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| Abstract: | In this paper, the interaction between hypocrellin A and indoles was studied by absorption and fluorescence spectroscopy. It was found tha hypocrellin A can form complexes with indoles and the complexes are of charge-transfer type. The electron-donating substitutents on indole ring, small hindrance of indole ring, large polar solvent, and neutral solution are favourable to the formation of the complexes. |
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| Keywords: | hypocrellin A indole comylex interaction |
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