Solvent Effects in Acid‐Catalyzed Biomass Conversion Reactions |
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| Authors: | Max A Mellmer Dr Canan Sener Dr Jean Marcel R Gallo Dr Jeremy S Luterbacher Dr David Martin Alonso Prof James A Dumesic |
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| Affiliation: | Department of Chemical and Biological Engineering, University of Wisconsin‐Madison, Madison, WI 53706 (USA) |
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| Abstract: | Reaction kinetics were studied to quantify the effects of polar aprotic organic solvents on the acid‐catalyzed conversion of xylose into furfural. A solvent of particular importance is γ‐valerolactone (GVL), which leads to significant increases in reaction rates compared to water in addition to increased product selectivity. GVL has similar effects on the kinetics for the dehydration of 1,2‐propanediol to propanal and for the hydrolysis of cellobiose to glucose. Based on results obtained for homogeneous Brønsted acid catalysts that span a range of pKa values, we suggest that an aprotic organic solvent affects the reaction kinetics by changing the stabilization of the acidic proton relative to the protonated transition state. This same behavior is displayed by strong solid Brønsted acid catalysts, such as H‐mordenite and H‐beta. |
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| Keywords: | biomass catalysis kinetics solvent effects sustainable chemistry |
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