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Mn2+在铝酸盐中的发光
引用本文:曾冬铭,付长城,程建良.Mn2+在铝酸盐中的发光[J].影像科学与光化学,2004,22(3):229-233.
作者姓名:曾冬铭  付长城  程建良
作者单位:中南大学校本部, 化学化工学院, 湖南, 长沙, 410083
摘    要:用金属硝酸盐、稀土氧化物和乙酸锰为原料,用燃烧法合成了Ce3+、Tb3+、Mn2+共激活的铝酸盐绿色荧光粉,在Ce3+和Tb3+共激活的铝酸盐体系中掺入Mn2+后,发射峰中出现锰的特征峰.通过对其结构的分析,对Mn2+发光和最佳掺杂量给出了合理的解释.同时研究了不同碱金属和碱土金属离子代替Mg2+时,对Mn2+发光的影响.

关 键 词:燃烧法  Mn2+  绿色荧光粉  发光  
收稿时间:2003-11-10

The Luminescence of Mn2+ in Aluminate
ZENG Dong-ming,FU Chang-cheng,CHENG Jian-liang.The Luminescence of Mn2+ in Aluminate[J].Imaging Science and Photochemistry,2004,22(3):229-233.
Authors:ZENG Dong-ming  FU Chang-cheng  CHENG Jian-liang
Affiliation:College of Chemistry and Chemical Engineering, Central of South University, Changsha 410083, Hunan, P. R. China
Abstract:Green-emitting phosphors of aluminate doped Ce~(3+),Tb~(3+),and Mn~(2+) were prepared by combustion synthesis.The phosphors of aluminate doped with Mn~(2+), Ce~(3+),and Tb~(3+) emitted character band of Mn~(2+).The luminescence and the optimum concentration of Mn~(2+) was interpreted by analysis of its structure.The luminescence of Mn~(2+) were reduced,especially the luminescence of Mn~(2+) were not observed in the phorphors while replaced Mg by Ca,Sr,and Ba.
Keywords:combustion synthesis  Mn~(2+)  green-emitting phosphors  luminescence
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