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The Oxygen‐Rich Beryllium Oxides BeO4 and BeO6 |
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| Authors: | Qingnan Zhang Dr Paul Jerabek Prof Mohua Chen Prof Mingfei Zhou Prof Gernot Frenking |
| Affiliation: | 1. Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai, China;2. Fachbereich Chemie, Philipps-Universit?t Marburg, Marburg, Germany |
| Abstract: | Two novel isomers of BeO4 with the structures OBeOOO and OBe(O3) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O2)2 in solid noble‐gas matrices. We also report the synthesis of the oxygen‐rich bis(ozonide) complex Be(O3)2 in the triplet state which has a D2d equilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations. |
| Keywords: | beryllium oxides matrix isolation ozonide complexes quantum chemical calculations |
