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The Aerobic Oxidation and C=C Bond Cleavage of Styrenes Catalyzed by Cerium(IV) Ammonium Nitrate (CAN)
Authors:Lei Yu  Yaping Huang  Zengbing Bai  Bingchun Zhu  Kehong Ding  Tian Chen  Yuanhua Ding  Yuguang Wang
Affiliation:1. Jiangsu Co‐innovation Center for Prevention and Control of Important Animal Infectious Diseases and Zoonoses, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, P. R. China;2. College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China
Abstract:The CAN‐catalyzed aerobic oxidation severed the C=C bond selectively through the single electron transfer mechanism, giving a green method to decompose olefins. Compared with the literature reported examples, this method required simple catalyst, cheap, abundant and clean oxidant and was very safe to operate due to the mild conditions.
Keywords:Aerobic oxidation  Single electron transfer (SET)  Green chemistry
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