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Intramolecular Aza‐Diels‐Alder Cyclization of a Dimerized Citral with Anilines Catalyzed by InCl3 |
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| Authors: | Yijang Chen Mani Ramanathan Shiuh‐Tzung Liu |
| Affiliation: | Department of Chemistry, National Taiwan University, 1, Sec. 4, Roosevelt Road, Taipei 106, Taiwan, Tel: +8862?33661661, Tel: +8862?33663831, Fax: +8862?33668670 |
| Abstract: | A series of aza‐polycyles containing octahydroacridine core were prepared via an intramolecular aza‐Diels‐Alder reaction of a dimerized citral with various aromatic amines. This reaction is efficiently catalyzed by InCl3 at ambient temperature to afford the corresponding cyclized products in moderate to good yields. |
| Keywords: | Aza‐Diels‐Alder Reaction Indium chloride Acridine |