RhIII‐Catalyzed Hydroacylation Reactions between N‐Sulfonyl 2‐Aminobenzaldehydes and Olefins |
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| Authors: | Tao Zhang Zisong Qi Xueyun Zhang Prof Lamei Wu Prof?Dr Xingwei Li |
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| Affiliation: | 1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China);2. College of Chemistry and Materials Science, South‐Central University for Nationalities, Wuhan 430074 (P. R. China) |
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| Abstract: | Metal‐catalyzed hydroacylation of olefins represents an important atom‐economic synthetic process in C?H activation. For the first time highly efficient RhIIICp*‐catalyzed hydroacylation was realized in the coupling of N‐sulfonyl 2‐aminobenzaldehydes with both conjugated and aliphatic olefins, leading to the synthesis of various aryl ketones. Occasionally, oxidative coupling occurred when a silver(I) oxidant was used. |
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| Keywords: | C H activation cyclization hydroacylation olefins rhodium |
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