Cyanoborohydride‐Based Ionic Liquids as Green Aerospace Bipropellant Fuels |
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| Authors: | Dr. Qinghua Zhang Dr. Ping Yin Dr. Jiaheng Zhang Prof. Dr. Jean'ne M. Shreeve |
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| Affiliation: | 1. Institute of Chemical Materials, China Academy of Engineering Physics (CAEP), Mianyang, 621900 (P.R. China);2. Department of Chemistry, University of Idaho, Moscow, Idaho, 83844‐2343 (USA), Fax: (+1)?208‐885‐9146 |
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| Abstract: | In propellant systems, the most common bipropellants are composed of two chemicals, a fuel (or reducer) and an oxidizer. Currently, the choices for propellant fuels rely mainly on hydrazine and its methylated derivatives, even though they are extremely toxic, highly volatile, sensitive to adiabatic compression (risk of detonation), and, therefore, difficult to handle. With this background, the search for alternative green propellant fuels has been an urgent goal of space science. In this study, a new family of cyanoborohydride‐based ionic liquids (ILs) with properties and performances comparable to hydrazine derivatives were designed and synthesized. These new ILs as bipropellant fuels, have some unique advantages including negligible vapor pressure, ultra‐short ignition delay (ID) time, and reduced synthetic and storage costs, thereby showing great application potential as environmentally friendly fuels in bipropellant formulations. |
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| Keywords: | hypergolic fuels ignition delay ionic liquids propellants green chemistry |
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