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A C2 Fragment as Four‐Electron σ Donor |
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| Authors: | Wolfgang Petz Diego M Andrada Markus Hermann Gernot Frenking Bernhard Neumüller |
| Affiliation: | 1. Fachbereich Chemie, Philipps‐Universit?t Marburg, Marburg, Germany;2. Donostia International Physics Center (DIPC), Donostia, Euskadi, Spain |
| Abstract: | The formation and X‐ray structure analysis of the PtIV complex (CH2C{PPh2C6H4}2)PtI2] is reported. The molecule possesses the orthometalated ligand (PPh3)2C→CH2, which serves via its C2 fragment as an unprecedented four‐electron σ donor. |
| Keywords: | Bonding analysis Carbone Four‐electron donor Platinum PtIV complex Quantum chemical calculations |
