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Facile Synthesis of Porous Dendritic Bimetallic Platinum–Nickel Nanocrystals as Efficient Catalysts for the Oxygen Reduction Reaction
Authors:Kamel Eid  Hongjing Wang  Victor Malgras  Zeid Abdullah Alothman  Yusuke Yamauchi  Liang Wang
Affiliation:1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang, P.R. China;2. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin, P.R. China;3. University of Chinese Academy of Sciences, Beijing, P.R. China;4. World Premier International (WPI) Research Center for Materials, Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki, Japan;5. Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia
Abstract:Certain bimetallic nanocrystals (NCs) possess promising catalytic properties for electrochemical energy conversion. Herein, we report a facile method for the one‐step synthesis of porous dendritic PtNi NCs in aqueous solution at room temperature that contrasts with the traditional multistep thermal decomposition approach. The dendritic PtNi NCs assembled by interconnected arms are efficient catalysts for the oxygen reduction reaction. This direct and efficient method is favorable for the up‐scaled synthesis of active catalysts used in electrochemical applications.
Keywords:alloys  dendritic structures  electrochemistry  nanoparticles  reduction
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