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Imaging the Magnetic Reversal of Isolated and Organized Molecular‐Based Nanoparticles using Magnetic Force Microscopy
Authors:Elena Pinilla‐Cienfuegos  Samuel Mañas‐Valero  Josep Canet‐Ferrer  Laure Catala  Talal Mallah  Alicia Forment‐Aliaga  Eugenio Coronado
Affiliation:1. Instituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, Spain;2. Institut de Chimie Moléculaire et des Matériaux d'Orsay, Université Paris‐Sud 11, CNRS, Orsay, France
Abstract:In the race towards miniaturization in nanoelectronics, magnetic nanoparticles (MNPs) have emerged as potential candidates for their integration in ultrahigh‐density recording media. Molecular‐based materials open the possibility to design new tailor‐made MNPs with variable composition and sizes, which benefit from the intrinsic properties of these materials. Before their implementation in real devices is reached, a precise organization on surfaces and a reliable characterization and manipulation of their individual magnetic behavior are required. In this paper, it is demonstrated how molecular‐based MNPs are accurately organized on surfaces and how the magnetic properties of the individual MNPs are detected and tuned by means of low‐temperature magnetic force microscopy (LT‐MFM) with variable magnetic field. The magnetization reversal on isolated and organized MNPs is investigated; in addition, the temperature dependence of their magnetic response is evaluated.
Keywords:magnetic force microscopy  magnetic nanoparticles  magnetization reversal  molecular‐based materials  Prussian‐blue analogues
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