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A Bismuth‐Based Metal–Organic Framework as an Efficient Visible‐Light‐Driven Photocatalyst
Authors:Guanzhi Wang  Qilong Sun  Prof Yuanyuan Liu  Prof Baibiao Huang  Prof Ying Dai  Xiaoyang Zhang  Xiaoyan Qin
Affiliation:1. State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100 (P.R. China);2. School of Physics, Shandong University, Jinan, 250100 (P.R. China)
Abstract:A visible‐light‐responsive bismuth‐based metal–organic framework (Bi‐mna) is demonstrated to show good photoelectric and photocatalytic properties. Combining experimental and theoretical results, a ligand‐to‐ligand charge transfer (LLCT) process is found to be responsible for the high performance, which gives rise to a longer lifetime of photogenerated charge carriers. Our results suggest that bismuth‐based MOFs could be promising candidates for the development of efficient visible‐light photocatalysts.
Keywords:bismuth  metal–  organic frameworks  photocatalysis  photoelectric properties  semiconducting materials
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