A Bismuth‐Based Metal–Organic Framework as an Efficient Visible‐Light‐Driven Photocatalyst |
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Authors: | Guanzhi Wang Qilong Sun Prof Yuanyuan Liu Prof Baibiao Huang Prof Ying Dai Xiaoyang Zhang Xiaoyan Qin |
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Affiliation: | 1. State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100 (P.R. China);2. School of Physics, Shandong University, Jinan, 250100 (P.R. China) |
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Abstract: | A visible‐light‐responsive bismuth‐based metal–organic framework (Bi‐mna) is demonstrated to show good photoelectric and photocatalytic properties. Combining experimental and theoretical results, a ligand‐to‐ligand charge transfer (LLCT) process is found to be responsible for the high performance, which gives rise to a longer lifetime of photogenerated charge carriers. Our results suggest that bismuth‐based MOFs could be promising candidates for the development of efficient visible‐light photocatalysts. |
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Keywords: | bismuth metal– organic frameworks photocatalysis photoelectric properties semiconducting materials |
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