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The First 3‐Connected SrSi2‐Type 3D Chiral Framework Constructed from {Ni6PW9} Building Units |
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| Authors: | Dr Xin‐Xiong Li Dr Wei‐Hui Fang Dr Jun‐Wei Zhao Prof Dr Guo‐Yu Yang |
| Affiliation: | 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China), Fax: (+86)?591‐8371‐0051;2. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004 (P. R. China);3. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing 100081 (P. R. China), Fax: (+86)?10‐68918572 |
| Abstract: | A novel 3‐connected SrSi2‐type 3D chiral framework constructed from hexa‐NiII‐cluster‐substituted polyoxometalate (POM) units Ni(enMe)2]3WO4]3Ni6(enMe)3(OH)3PW9O34]2?9H2O ( 1 ) (enMe=1,2‐diaminopropane) has been made from a hydrothermal synthetic method. This POM represents the first 3D framework based on {Ni6PW9} units and {WO4} connectors. |
| Keywords: | chiral framework cluster compounds nickel polyoxometalate |
