Ba3P5N10Br:Eu2+: A Natural‐White‐Light Single Emitter with a Zeolite Structure Type |
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| Authors: | Alexey Marchuk Prof. Dr. Wolfgang Schnick |
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| Affiliation: | Department Chemie, Lehrstuhl für Anorganische Festk?rperchemie, Ludwig‐Maximilians‐Universit?t München, Butenandtstrasse 5–13, 81377 München (Germany) |
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| Abstract: | ![]()
Illumination sources based on phosphor‐converted light emitting diode (pcLED) technology are nowadays of great relevance. In particular, illumination‐grade pcLEDs are attracting increasing attention. Regarding this, the application of a single warm‐white‐emitting phosphor could be of great advantage. Herein, we report the synthesis of a novel nitridophosphate zeolite Ba3P5N10Br:Eu2+. Upon excitation by near‐UV light, natural‐white‐light luminescence was detected. The synthesis of Ba3P5N10Br:Eu2+ was carried out using the multianvil technique. The crystal structure of Ba3P5N10Br:Eu2+ was solved and refined by single‐crystal X‐ray diffraction analysis and confirmed by Rietveld refinement and FTIR spectroscopy. Furthermore, spectroscopic luminescence measurements were performed. Through the synthesis of Ba3P5N10Br:Eu2+, we have shown the great potential of nitridophosphate zeolites to serve as high‐performance luminescence materials. |
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| Keywords: | high‐pressure chemistry high‐temperature chemistry luminescence nitrides zeolites |
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