Excavated Cubic Platinum–Tin Alloy Nanocrystals Constructed from Ultrathin Nanosheets with Enhanced Electrocatalytic Activity |
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| Authors: | Qiaoli Chen Yanan Yang Zhenming Cao Dr Qin Kuang Guifen Du Dr Yaqi Jiang Prof Zhaoxiong Xie Prof Lansun Zheng |
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| Affiliation: | State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P.R. China |
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| Abstract: | Excavated polyhedral noble‐metal materials that were built by the orderly assembly of ultrathin nanosheets have both large surface areas and well‐defined facets, and therefore could be promising candidates for diverse important applications. In this work, excavated cubic Pt–Sn alloy nanocrystals (NCs) with {110} facets were constructed from twelve nanosheets by a simple co‐reduction method with the assistance of the surface regulator polyvinylpyrrolidone. The specific surface area of the excavated cubic Pt–Sn NCs is comparable to that of commercial Pt black despite their larger particle size. The excavated cubic Pt–Sn NCs exhibited superior electrocatalytic activity in terms of both the specific area current density and the mass current density towards methanol oxidation. |
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| Keywords: | alloys electrocatalysis nanocrystals platinum tin |
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