Docking Strategy To Construct Thermostable,Single‐Crystalline,Hydrogen‐Bonded Organic Framework with High Surface Area |
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| Authors: | Dr Ichiro Hisaki Yuto Suzuki Eduardo Gomez Dr Boiko Cohen Dr Norimitsu Tohnai Prof?Dr Abderrazzak Douhal |
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| Affiliation: | 1. Department of Material and Life Science, Graduate School of Engineering, Osaka University, Suita, Osaka, Japan;2. Departamento de Quimica Fisica, Facultad de Ciencias Ambientales y Bioquimica, and INAMOL, Universidad de Castilla-La Mancha, Toledo, Spain |
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| Abstract: | Enhancing thermal and chemical durability and increasing surface area are two main directions for the construction and improvement of the performance of porous hydrogen‐bonded organic frameworks (HOFs). Herein, a hexaazatriphenylene (HAT) derivative that possesses six carboxyaryl groups serves as a suitable building block for the systematic construction of thermally and chemically durable HOFs with high surface area through shape‐fitted docking between the HAT cores and interpenetrated three‐dimensional network. A HAT derivative with carboxybiphenyl groups forms a stable single‐crystalline porous HOF that displays protic solvent durability, even in concentrated HCl, heat resistance up to 305 °C, and a high Brunauer–Emmett–Teller surface area SA(BET)] of 1288 m2 g?1. A single crystal of this HOF displays anisotropic fluorescence, which suggests that it would be applicable to polarized emitters based on robust functional porous materials. |
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| Keywords: | carboxylic acids crystal engineering fluorescence hydrogen bonds porous organic frameworks |
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