Superelastic Organic Crystals |
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Authors: | Prof?Dr Satoshi Takamizawa Yasuhiro Miyamoto |
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Affiliation: | Graduate School of Nanobioscience, Yokohama City University, Seto 22‐2, Kanazawa‐ku, Yokohama 236‐0027 (Japan) |
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Abstract: | Superelastic materials (crystal‐to‐crystal transformation pseudo elasticity) that consist of organic components have not been observed since superelasticity was discovered in a Au‐Cd alloy in 1932. Superelastic materials have been exclusively developed in metallic or inorganic covalent solids, as represented by Ti‐Ni alloys. Organosuperelasticity is now revealed in a pure organic crystal of terephthalamide, which precisely produces a large motion with high repetition and high energy storage efficiency. This process is driven by a small shear stress owing to the low density of strain energy related to the low lattice energy. |
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Keywords: | amides crystal engineering mechanical properties phase transitions terephthalamide |
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