K4[PbSe4]⋅en⋅NH3: A Non‐Oxide,Non‐Halide Inorganic Lead(IV) Compound |
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| Authors: | Dipl‐Chem Günther Thiele Thomas Krüger Prof?Dr Stefanie Dehnen |
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| Affiliation: | Fachbereich Chemie und Wissenschaftliches Zentrum für Materialwissenschaften, Philipps‐Universit?t Marburg, Hans‐Meerwein‐Strasse, 35032 Marburg (Germany) http://www.uni‐marburg.de/fb15/ag‐dehnen |
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| Abstract: | The first inorganic lead(IV) compound without oxygen, nitrogen or halogen ligands attached to the lead atom was obtained as the potassium salt of the tetraselenidoplumbate(IV) anion PbIVSe4]4?. It is stable under inert conditions which may enable the transfer of the chemistry of chalcogenidogermanate(IV) or chalcogenidostannate(IV) materials, to the lead homologues. |
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| Keywords: | DFT calculations lead MP2 calculations plumbates structure elucidation |
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