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Geometry of the canonical Van Vleck transformation
Authors:Flemming Jørgensen
Affiliation:Flinten 10 4700 N?stved Denmark
Abstract:Bloch's transformation urn:x-wiley:00207608:media:qua24992:qua24992-math-0001 from the zeroth‐order space for a perturbation problem to the corresponding space of exact eigenvectors, was found as a geometrically defined alternative to the algebraically constructed Van Vleck transformation. Klein's theorem of uniqueness transferred some of this geometrical interpretation to its canonical form urn:x-wiley:00207608:media:qua24992:qua24992-math-0002. Quite recently Kvaal has taken a large step further by writing urn:x-wiley:00207608:media:qua24992:qua24992-math-0003 as a product of commuting planar rotations, obtained by describing urn:x-wiley:00207608:media:qua24992:qua24992-math-0004 and urn:x-wiley:00207608:media:qua24992:qua24992-math-0005 in terms of certain principal vectors and canonical angles. Kvaal's approach is now developed further, using a new commutation relation which simplifies algebraic manipulations substantially. It allows for a simple definition of an operator urn:x-wiley:00207608:media:qua24992:qua24992-math-0006 for the angle between urn:x-wiley:00207608:media:qua24992:qua24992-math-0007 and urn:x-wiley:00207608:media:qua24992:qua24992-math-0008 which has Kvaal's vectors and angles as eigenvectors and eigenvalues. Klein's theorem is refined in various ways. The impact of the approach on a number of previous results is considered. © 2015 Wiley Periodicals, Inc.
Keywords:canonical Van Vleck transformation  effective Hamiltonian  theorem of uniqueness  geometrical interpretation  commutation relations  special value decomposition
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