High‐Level Incorporation of Silver in Gold Nanoclusters: Fluorescence Redshift upon Interaction with Hydrogen Peroxide and Fluorescence Enhancement with Herbicide |
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| Authors: | Dr Guijian Guan Dr Yongqing Cai Dr Shuhua Liu Dr Haidong Yu Dr Shiqiang Bai Dr Yuan Cheng Dr Tao Tang Dr M S Bharathi Prof Yong‐Wei Zhang Prof Ming‐Yong Han |
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| Affiliation: | 1. Institute of High Performance Computing, A*STAR, Singapore, Singapore;2. Institute of Materials Research and Engineering, A*STAR, Singapore, Singapore |
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| Abstract: | High‐level incorporation of Ag in Au nanoclusters (NCs) is conveniently achieved by controlling the concentration of Ag+ in the synthesis of bovine serum albumin (BSA)‐protected Au NCs, and the resulting structure is determined to be bimetallic Ag28Au10‐BSA NCs through a series of characterizations including energy‐dispersive X‐ray spectroscopy, mass spectroscopy, and X‐ray photoelectron spectroscopy, together with density functional theory simulations. Interestingly, the Ag28Au10 NCs exhibit a significant fluorescence redshift rather than quenching upon interaction with hydrogen peroxide, providing a new approach to the detection of hydrogen peroxide through direct comparison of their fluorescence peaks. Furthermore, the Ag28Au10 NCs are also used for the sensitive and selective detection of herbicide through fluorescence enhancement. The detection limit for herbicide (0.1 nm ) is far below the health value established by the U.S. Environmental Protection Agency; such sensitive detection was not achieved by using AuAg NCs with low‐level incorporation of Ag or by using the individual metal NCs. |
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| Keywords: | density functional calculations fluorescence hydrogen peroxide herbicides nanoclusters |
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