Stereodynamics of the reactions Ne+H2+/Ne+D2+/Ne+T2 |
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| Authors: | Xiao Jing Yang Chuan-Lu and Wang Mei-Shan |
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| Affiliation: | School of Physics, Ludong University, Yantai 264025, China |
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| Abstract: | The vector correlations between products and reagents for the reactions Ne+H + 2 , Ne+D + 2 , and Ne+T + 2 are cal- culated by means of the quasi-classical trajectory method on a new potential energy surface constructed by Lüet al. [J. Chem. Phys. 2010 132, 014303]. The polarization-dependent differential cross-sections (2π/σ)(dσ 00 /dω t ), (2π/σ)(dσ 20 /dω t ), (2π/σ)(dσ 22+ /dω t ), and (2π/σ)(dσ 21 /dω t ), and the distributions of P (θ r ), P (φ r ), and P (θ r ,φ r ) are calculated. The isotopic effect, which is associated with the difference in mass factor among the three reactions, is revealed. |
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| Keywords: | stereodynamics quasi-classical trajectory isotopic effect vector correlation |
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