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Nickel(II) complex containing N‐(4,5‐dihydrooxazol‐2‐yl)benzamide ligands: highly efficient catalyst for Heck coupling reactions
Authors:Junke Wang  Yingxiao Zong  Shenglong Wei  Yi Pan
Affiliation:1. Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities, College of Chemistry and Chemical Engineering, Hexi University, Zhangye, China;2. School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China;3. Gansu Engineering Laboratory of Applied Fungus, Hexi University, Zhangye, China
Abstract:Heck reaction catalyzed by Ni(II) containing N‐(4,5‐dihydrooxazol‐2‐yl) benzamide has been developed. The coupling of alkenes with aryl iodide or aryl bromide in the presence of potassium carbonate in DMF provides the corresponding products with moderate to good yields. This method possesses obvious advantages such as low‐cost catalyst and simple experimental operation. Copyright © 2014 John Wiley & Sons, Ltd.
Keywords:nickel(II) complex  Heck reaction  aryl iodides  aryl bromides
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