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A Solution‐Processable Donor–Acceptor Compound Containing Boron(III) Centers for Small‐Molecule‐Based High‐Performance Ternary Electronic Memory Devices
Authors:Dr Chun‐Ting Poon  Dr Di Wu  Dr Wai Han Lam  Prof?Dr Vivian Wing‐Wah Yam
Affiliation:Institute of Molecular Functional Materials (Area of Excellence Scheme, University Grants Committee, Hong Kong) and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (P.R. China)
Abstract:A novel small‐molecule boron(III)‐containing donor–acceptor compound has been synthesized and employed in the fabrication of solution‐processable electronic resistive memory devices. High ternary memory performances with low turn‐on (VTh1=2.0 V) and distinct threshold voltages (VTh2=3.3 V), small reading bias (1.0 V), and long retention time (>104 seconds) with a large ON/OFF ratio of each state (current ratio of “OFF”, “ON1”, and “ON2”=1:103:106) have been demonstrated, suggestive of its potential application in high‐density data storage. The present design strategy provides new insight in the future design of memory devices with multi‐level transition states.
Keywords:boron  donor–  acceptor systems  organic electronics  ternary memory devices
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