| 高分子链对激发态芳烃和胺相互作用的影响 |
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| 引用本文： | 李妙贞,常志英,王尔鑑.高分子链对激发态芳烃和胺相互作用的影响[J].影像科学与光化学,1983,1(1):39-44. |
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| 作者姓名： | 李妙贞 常志英 王尔鑑 |
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| 作者单位： | 中国科学院感光化学研究所 |
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| 摘 要： | 本文研究了在激发状态下芳烃(受体)和脂肪胺(给体)的相互作用以及高分子链在其中的影响。结果表明,高分子胺与不带高分子链的胺相比,其对激发态芳烃的淬灭速度和形成激基复合物的能力都强得多,并且激基复合物光谱发生明显红移。
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| 收稿时间： | 1982-01-09 |
THE EFFECT OF POLYMER CHAIN ON THE INTERACTION BETWEEN EXCITED AROMATIC HYDROCARBONSAND AMINES |
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| LI MIAO-ZHEN,CHANG ZHI-YING,WANG EK-JIAN.THE EFFECT OF POLYMER CHAIN ON THE INTERACTION BETWEEN EXCITED AROMATIC HYDROCARBONSAND AMINES[J].Imaging Science and Photochemistry,1983,1(1):39-44. |
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| Authors: | LI MIAO-ZHEN CHANG ZHI-YING WANG EK-JIAN |
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| Affiliation: | Institute of Photographic Chemistry, Academia Sinica |
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| Abstract: | The excited state interaction of some aromatic hydrocarbon (acceptor)-aliphatic amine (donor) systems and the effect of polymer chain have been studied. The results obtained show that the rate of quenching of the excited aromatic hydrocarbon by polymer -amine (P-TEA) and their ability to form exciplex are much higher than those by ordinary tertiary amine. A pronounced red shift of exciplex emission bands is observed in the case of P-TEA. |
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