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Two‐Dimensional Nanoporous Networks Formed by Liquid‐to‐Solid Transfer of Hydrogen‐Bonded Macrocycles Built from DNA Bases |
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| Authors: | Nerea Bilbao Iris Destoop Prof. Steven De Feyter Dr. David González‐Rodríguez |
| Affiliation: | 1. Nanostructured Molecular Systems and Materials Group, Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, 28049 Madrid (Spain);2. Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven–University of Leuven, Celestijnenlaan 200 F, 3001 Leuven (Belgium) |
| Abstract: | We present an approach that makes use of DNA base pairing to produce hydrogen‐bonded macrocycles whose supramolecular structure can be transferred from solution to a solid substrate. A hierarchical assembly process ultimately leads to two‐dimensional nanostructured porous networks that are able to host size‐complementary guests. |
| Keywords: | macrocycles porous networks self‐assembly supramolecular chemistry surface assembly |