| Abstract: | Herein, we report the syntheses of silicon‐ and tin‐containing open‐chain and eight‐membered‐ring compounds Me2Si(CH2SnMe2X)2 ( 2 , X=Me; 3 , X=Cl; 4 , X=F), CH2(SnMe2CH2I)2 ( 7 ), CH2(SnMe2CH2Cl)2 ( 8 ), cyclo‐Me2Sn(CH2SnMe2CH2)2SiMe2 ( 6 ), cyclo‐(Me2SnCH2)4 ( 9 ), cyclo‐Me(2?n)XnSn(CH2SiMe2CH2)2SnXnMe(2?n) ( 5 , n=0; 10 , n = 1, X= Cl; 11 , n=1, X= F; 12 , n=2, X= Cl), and the chloride and fluoride complexes NEt4cyclo‐ Me(Cl)Sn(CH2SiMe2CH2)2Sn(Cl)Me?F] ( 13 ), PPh4cyclo‐Me(Cl)Sn(CH2SiMe2CH2)2Sn(Cl)Me?Cl] ( 14 ), NEt4cyclo‐Me(F)Sn(CH2SiMe2CH2)2Sn(F)Me?F] ( 15 ), NEt4]2cyclo‐Cl2Sn(CH2SiMe2CH2)2SnCl2?2 Cl] ( 16 ), MMe2Si(CH2Sn(Cl)Me2)2?Cl] ( 17 a , M=PPh4; 17 b , M=NEt4), NEt4Me2Si(CH2Sn(Cl)Me2)2?F] ( 18 ), NEt4Me2Si(CH2Sn(F)Me2)2?F] ( 19 ), and PPh4Me2Si(CH2Sn(Cl)Me2)2?Br] ( 20 ). The compounds were characterised by electrospray mass‐spectrometric, IR and 1H, 13C, 19F, 29Si, and 119Sn NMR spectroscopic analysis, and, except for 15 and 18 , single‐crystal X‐ray diffraction studies. |
