Advances in Iodine(III)‐Mediated Halogenations: A Versatile Tool to Explore New Reactivities and Selectivities |
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| Authors: | Andreas M Arnold Anna Ulmer Dr Tanja Gulder |
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| Affiliation: | 1. http://www.halogene.ch.tum.de;2. Department Chemie and Catalysis Research Center (CRC), Technische Universit?t München, Garching, Germany |
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| Abstract: | Within the repertoire of organic chemical transformations, the halogenation of substrates is among the most versatile, reliable, and broadly applicable reactions. Although a multitude of different methods are known today, there is still a huge demand for novel and, in particular, catalytic halogenation methods that exhibit new reactivities and selectivities. The class of hypervalent iodanes meets exactly these needs and thus offers a great opportunity to fuel this highly desirable direction within the field of halogenation chemistry. This Concept gives a short overview of recent examples focusing on selective and/or mechanistically unusual halogenations. |
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| Keywords: | halogenation hypervalent iodine oxidation reaction mechanisms selectivity |
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