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Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents |
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| Authors: | Dr. Michael Brown Dr. Ravi Kumar Dr. Julia Rehbein Prof. Dr. Thomas Wirth |
| Affiliation: | 1. School of Chemistry, Cardiff University, Cardiff, UK;2. Organische Chemie, Universit?t Hamburg, Hamburg, Germany;3. http://www.cf.ac.uk/chemy/wirth(+44)?29‐2087‐6968 |
| Abstract: | A stereoselective hypervalent iodine‐promoted oxidative rearrangement of 1,1‐disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α‐arylated ketones without the use of transition metals from readily accessible alkenes. |
| Keywords: | alkenes arylation hypervalent iodine oxidation rearrangement |