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Ultrahigh‐Resolution Diffusion‐Ordered Spectroscopy |
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| Authors: | Dr Mohammadali Foroozandeh Dr Laura Castañar Dr Lucas G Martins Dr Davy Sinnaeve Guilherme Dal Poggetto Prof Claudio F Tormena Dr Ralph W Adams Prof Gareth A Morris Dr Mathias Nilsson |
| Affiliation: | 1. School of Chemistry, University of Manchester, Manchester, UK;2. Chemistry Institute, University of Campinas, Campinas, SP, Brazil;3. Department of Organic and Macromolecular Chemistry, Ghent University, Ghent, Belgium |
| Abstract: | Diffusion‐ordered spectroscopy (DOSY) is an effective method for the analysis of intact mixtures, but the quality of results is critically limited by resolution in the NMR dimension. A new experiment integrating diffusion weighting into the PSYCHE method for pure shift NMR spectroscopy allows DOSY spectra to be measured with ultrahigh NMR resolution at improved sensitivity. |
| Keywords: | analytical methods diffusion DOSY NMR spectroscopy PSYCHE |
