| 基于甲胺铅碘钙钛矿太阳电池中有效载流子产率的厚度拟合优化分析 |
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| 引用本文： | 刘桂林,张忠扬,席曦,东为富,陈国庆,朱华新.基于甲胺铅碘钙钛矿太阳电池中有效载流子产率的厚度拟合优化分析[J].人工晶体学报,2019,48(7):1308-1313. |
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| 作者姓名： | 刘桂林 张忠扬 席曦 东为富 陈国庆 朱华新 |
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| 作者单位： | 江南大学理学院,无锡214122;江南大学化学与材料工程学院,无锡214122;光响应功能分子材料国际联合研究中心,无锡214122;浙江大学海洋学院,杭州,310058;江南大学理学院,无锡,214122;江南大学化学与材料工程学院,无锡214122;光响应功能分子材料国际联合研究中心,无锡214122 |
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| 基金项目： | 国家自然科学基金(61804066);江苏省自然科学基金(BK20180601,BK20180596);江南大学高校自主科研基金(JUSRP11834,JUSRP11834B);江苏省博士后基金(2018K112C,2018K113C) |
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| 摘 要： | 有机金属钙钛矿太阳电池已经吸引了科研界广泛的研究热情,然而,钙钛矿太阳电池的发展仍需要持续的研究,这其中,活性层最优厚度的优化仍依赖大量的实验研究,这种方式耗费巨大的财力、物力及人员时间和精力,而对于活性层厚度优化与光电子产率之间的关系仍缺乏相应的理论研究。本文提出了一种有效载流子产率的概念,并利用光学传输矩阵方程,对其进行厚度的优化拟合。通过计算发现,当光子流密度处于AM1.5G条件下时,各功能层的厚度均对钙钛矿太阳能电池的有效载流子产率有很大的影响。研究显示,在反式器件结构中,当空穴传输层与电子传输层的厚度分别为55nm及40nm时,器件的光电转换效率最优。该方法为加快钙钛矿太阳能电池的优化提供了一种快速有效的手段。
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| 关 键 词： | 钙钛矿太阳电池 有效载流子 产生速率 厚度拟合 |
Optimizing of Thickness Combination in MAPbI3 Inverted Perovskite Solar Cells with the Concept of Effective Carrier Generation |
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| LIU Gui-lin,ZHANG Zhong-yang,XI Xi,DONG Wei-fu,CHEN Guo-qing,ZHU Hua-xin.Optimizing of Thickness Combination in MAPbI3 Inverted Perovskite Solar Cells with the Concept of Effective Carrier Generation[J].Journal of Synthetic Crystals,2019,48(7):1308-1313. |
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| Authors: | LIU Gui-lin ZHANG Zhong-yang XI Xi DONG Wei-fu CHEN Guo-qing ZHU Hua-xin |
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| Affiliation: | (School of Science,Jiangnan University,Wuxi 214122,China;School of Chemical and Material Engineerging,Jiangnan University,Wuxi 214122,China;International Joint Research Center for Photoresponse Functional Molecular Materials,Wuxi 214122,China;College of Ocean,Zhejiang University,Hangzhou,310058,China) |
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| Abstract: | Organic-metal hybrid perovskite solar cells are attracting a great deal of attention to the scientific community.However,the academic system of perovskite solar cells still needs further development.Most of the active layers’thickness combinations are carried out from practical experiments on constant thickness.The theoretic process for this subject is still unsubstantial.In this paper,a concept of effective carrier generation rate,based on light intensity distribution,is given.For maximizing this rate,the thickness combination of active layers can be obtained.In order to keep the simulation process closer to practical fabrication,photon flux distribution of AM 1.5G and transmissivity of substrates were introduced into the calculation.It was found that the best optimization for hole transport layer and electron transport layer was 55 nm and 40 nm,respectively.The main contribution of this method is that it gives a rapid search range of thickness combination of donor and acceptor layers. |
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| Keywords: | perovskite solar cell effective carrier generation rate thickness combination |
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