| Influence of reagent vibration on the stereodynamics of the Li ＋ HF → LiF ＋ H reaction |
| |
| 作者姓名： | 李淑娟 石英 解廷献 金明星 |
| |
| 作者单位： | [1]Institute of Atomic and Molecular Physics, 3ilin University, Changchun 130012, China [2]Department of Physics, Dalian 3iaotong University, Dalian 116028, China |
| |
| 基金项目： | Project supported by Jilin University, China （Grant No. 419080106440）, the Chinese National Fusion Project for ITER （Grant No. 2010GB104003）, and the National Natural Science Foundation of China （Grant No. 10974069）. Many thanks to Prof. Haqn Ke-Li Han for providing the stereodynamics program. |
| |
| 摘 要： | ![]()
We investigate the influence of reagent vibration on the stereodynamics of the title reaction by the quasi-classical trajectory on the Aguado-Paniagua2-potential energy surface developed by Aguado et al.(J.Chem.Phys.1997 106 1013).The cross sections and reaction probability as functions of the reagent vibration are calculated in the centre-ofmass frame.The product angular distributions of p(θr),p(φr),and p(θr,φr),which reflect the vector correlation,are also presented and discussed.The results indicate that the vector properties are sensitively affected by the vibrational excitation.
|
| 关 键 词： | quasi-classical trajectory vector correlation cross sections stereodynamics |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
