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Powder x-ray diffraction and Rietveld analysis of (C_2H_5NH_3)_2CuCl_4
Affiliation:1.Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;2.Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;3.School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100190, China;4.School of Material Science and Engineering, Hebei University of Technology, Tianjin 300130, China
Abstract:Structural properties of the organic-inorganic hybrid (C2H5NH3)2CuCl4 (EA2CuCl4) have been investigated by means of x-ray powder diffraction and Rietveld analysis. A structural phase transition from Pbca to Aba2 occurs at T4=240 K, which results in a paraelectric-ferroelectric phase transition. The release of the Jahn-Teller distortion with increasing temperature toward T4 is revealed by the structural analysis.
Keywords:organic-inorganic hybrid  x-ray diffraction  (C2H5NH3)2CuCl4  
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