Phenylene‐Coated Magnetic Nanoparticles that Boost Aqueous Asymmetric Transfer Hydrogenation Reactions |
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| Authors: | Dr Xiaoshuang Gao Rui Liu Dacheng Zhang Meng Wu Tanyu Cheng Prof Guohua Liu |
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| Affiliation: | Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234 (P. R. China) |
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| Abstract: | Phenylene‐coated organorhodium‐functionalized magnetic nanoparticles are developed through co‐condensation of chiral 4‐(trimethoxysilyl)ethyl)phenylsulfonyl‐1,2‐diphenylethylene‐diamine and 1,4‐bis(triethyoxysilyl)benzene onto Fe3O4 followed complexation with {Cp*RhCl2}2]. This magnetic catalyst exhibits excellent catalytic activity and high enantioselectivity in asymmetric transfer hydrogenation in aqueous medium. Such activity is attributed to the high hydrophobicity and the confined nature of the chiral organorhodium catalyst. The magnetic catalyst can be easily recovered by using a small external magnet and it can be reused for at least 10 times without loss of its catalytic activity. This characteristic makes it an attractive catalyst for environmentally friendly organic syntheses. |
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| Keywords: | asymmetric transfer catalysts heterogeneous catalysis magnetic nanoparticles magnetic separation mesoporous materials |
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